Rate constants for reaction of the chloromethylidyne radical with olefins, alkynes, chloroalkanes, hydrogen, and oxygen
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2483-2487
- https://doi.org/10.1039/j19690002483
Abstract
Decay of chloromethylidyne (CCI) in flash-photolysed CF2CCl2+ N2 mixtures was monitored by kinetic spectroscopy. Rate constants for reactions at 298°± 3°K with olefins, acetylene, and propyne correlate with their ionization potentials, suggesting that reaction occurs by attack of the π-systems. Rate constants were determined for some reactions of CCl with saturated compounds, hydrogen and oxygen.Keywords
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