Homogeneous decarbonylation of ethyl formate at rhodium. Evidence for the formation of a cis-hydride(ethoxycarbonyl) intermediate through CH bond cleavage
- 28 June 1988
- journal article
- research article
- Published by Elsevier in Journal of Organometallic Chemistry
- Vol. 348 (1) , C9-C11
- https://doi.org/10.1016/0022-328x(88)80349-8
Abstract
No abstract availableKeywords
This publication has 5 references indexed in Scilit:
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- Intra- and intermolecular activation of sp2 carbon-hydrogen bonds at rhodium(I) and iridium(I) metal centers. X-ray structure of the cis .sigma.-cyclooctadienyl hydride [{N(CH2CH2PPh2)3}IrH(.sigma.-C8H11)]BPh4.cntdot.CH3COCH3Organometallics, 1986
- Reactions of formic acid. 1. The iridium-catalyzed synthesis of acetic acid from methyl formateOrganometallics, 1982