Fluorhaltige Nitrile als Komplexliganden / Fluorine Containing Nitriles as Complex Ligands
Open Access
- 1 October 1979
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 34 (10) , 1461-1463
- https://doi.org/10.1515/znb-1979-1024
Abstract
N-Cyano-sulfurdifluoride-imide NC-NSF2 and N-cyano-sulfuroxide-difluoride-imide NC-NSOF2 will react with AsFs to give the N-bonded nitrile adducts F5As · NC-NSF2 (F5As · NC-NSOF2). With [M(CO)5SO2]+AsF6- (M=Mn,Re) the expected complexes [(CO)5MNC-NSF2]+AsF6- [(CO)5MNC-NSF2]+AsF6-are formed in quantitative yield.Keywords
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