A study of the phase transition behavior of internally mixed ammonium sulfate - malonic acid aerosols
Open Access
- 1 September 2004
- journal article
- Published by Copernicus GmbH in Atmospheric Chemistry and Physics
- Vol. 4 (5) , 1451-1459
- https://doi.org/10.5194/acp-4-1451-2004
Abstract
This is a study into the phase transitions of aerosol composed of the ternary system ammonium sulfate (AS) - malonic acid (MA) - water using infrared extinction spectroscopy. Twelve compositions were studied in both deliquescence and efflorescence mode experiments. The presence of a MA fraction, by dry mass, (fMA) of 0.1 in an AS aerosol altered the relative humidity at which the phase transitions occur in an atmospherically significant manner. For compositions with 0.25<fMAfMA=0.9, the crystallization relative humidity of MA was lowered from RH=6% to less than 1%. Similarly, at fMA=0.4, the AS component did not crystallize. The atmospheric implications of the results are discussed.Keywords
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