Synthesis and reactivity of vinylimido complexes of titanocene

1 January 1990

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 20,p. 1452-1454
https://doi.org/10.1039/c39900001452

Abstract

Tabbe's reagent (Cp₂TiCH₂·AlMe₂Cl) or titanocene metallacyclobutanes react with nitriles in the presence of a Lewis base such as trimethylphosphine to afford vinylimido complexes of titanocene; these undergo follow-up reactions with unsaturated organic molecules to yield new heterocyclic compounds of titanocene.

Keywords

AFFORD VINYLIMIDO
YIELD NEW
LEWIS BASE
UNSATURATED ORGANIC
ORGANIC MOLECULES
HETEROCYCLIC COMPOUNDS
TITANOCENE METALLACYCLOBUTANES
TITANOCENE TABBE'S

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