Replacement of OH by OD in layer silicates, and identification of the vibrations of these groups in infra-red spectra
- 1 December 1970
- journal article
- Published by Mineralogical Society in Mineralogical Magazine
- Vol. 37 (292) , 869-879
- https://doi.org/10.1180/minmag.1970.037.292.01
Abstract
Summary: Conditions necessary for exchange between lattice OH groups and D2O in expanding layer silicates are reported. From spectral changes in the 200–1200 cm−1 region resulting from this exchange, in-plane librations of OH co-ordinated to (A1A1), (A1Mg), (A1Fe3+), and (MgMgMg) have been identified in montmorillonite, beidellite, saponite, hectorite, and vermiculite. Both in-plane and out-of-plane librations have been identified for pyrophyllite and celadonite, from comparison of synthetic specimens containing OD with natural or synthetic OH forms. Comparison of hydrogen and deuterium forms of Mg- and Ni-talcs leads to the identification of translational and librational OH vibrations.Keywords
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