An anomalous X-ray scattering study of an aqueous solution of ZnCl2
- 6 November 1989
- journal article
- Published by IOP Publishing in Journal of Physics: Condensed Matter
- Vol. 1 (44) , 8575-8582
- https://doi.org/10.1088/0953-8984/1/44/028
Abstract
Concentrated aqueous solutions of ZnCl2 have been studied by the anomalous X-ray scattering (AXS) technique at the Zn K-absorption edge. The hydration number around Zn2+ was found to be 5.7 at a distance of 0.210 nm in the 0.98 kmol m-3 ZnCl2 aqueous solution. On the other hand, in the 2.85 kmol m-3 ZnCl2 aqueous solution the hydration number becomes 6.2 with a distance of 0.215 nm. The present study has demonstrated the capability of the AXS technique for structural study of aqueous solutions containing heavy metallic ions.Keywords
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