A novel synthetic approach to mitomycins. One step synthesis of a 5,10‐dioxo‐1H‐pyrrolo[1,2‐a]benz[f]indole
- 1 January 1979
- journal article
- research article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 98 (4) , 251-252
- https://doi.org/10.1002/recl.19790980421
Abstract
A new method for the synthesis of pyrrolo[1,2‐a]indoles, starting from enamines via 1,5‐dipolar cyclization is described. The method is considered to be useful for the synthesis of mitomycin type of compounds.Keywords
This publication has 13 references indexed in Scilit:
- The reaction of enamines with dimethyl acetylenedicarboxylate in polar solventsTetrahedron Letters, 1978
- Synthesis of Pyrrolo[1,2-a]indoles and Related SystemsHETEROCYCLES, 1978
- Synthetiic studies toward mitomycins. III. Total syntheses of mitomycins A and CTetrahedron Letters, 1977
- Synthetic studies toward mitomycins. 2. Total synthesis of dl-porfiromycinJournal of the American Chemical Society, 1977
- The Intramolecular Hydrogen Abstraction Reaction in the Photolysis of Aminated 1,4-NaphthoquinonesBulletin of the Chemical Society of Japan, 1977
- Photolysis of Amino-substituted 1,4-Naphthoquinones. A Novel Synthesis of Heterocyclic QuinonesHETEROCYCLES, 1977
- Reactions of thiophenes with acetylenes in polar solvents; a novel annulation reactionTetrahedron Letters, 1976
- Photochemical and thermal reactions of naphthoquinones and ynamines. Formations of intermediate cyclobutadienesThe Journal of Organic Chemistry, 1972
- The Mitomycins and PorfiromycinsPublished by Springer Nature ,1967
- Enamine Chemistry. II. Reactions with Acetylenedicarboxylates1The Journal of Organic Chemistry, 1963