A Chiral Molecular Based Metamagnet Prepared from Manganese Ions and a Chiral Triplet Organic Radical as a Bridging Ligand
- 26 May 1999
- journal article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 38 (11) , 1601-1603
- https://doi.org/10.1002/(sici)1521-3773(19990601)38:11<1601::aid-anie1601>3.0.co;2-#
Abstract
Below 5.4 K the one-dimensional polymeric complex made up of manganese(II) hexafluoroacetylacetonate units and bridging bisaminooxylbenzene diradicals (shown in the picture) behaves as a metamagnet. The R-helical chain not only contains an S-configured chiral carbon center, but also an R-configured C2 -symmetric chiral skeleton of the organic ligand.This publication has 0 references indexed in Scilit: