Reactions of Organometallic Reagents with Halogenophosphazene Cyclic Trimers, Tetramers, and High Polymers
- 19 December 1983
- journal article
- research article
- Published by Taylor & Francis in Phosphorus and Sulfur and the Related Elements
- Vol. 18 (1-3) , 267-270
- https://doi.org/10.1080/03086648308076017
Abstract
Three main mechanistic pathways are now evident when Grignard, organolithium, organocopper, or transition metal anions are used as reagents for reactions with halogeno-phosphazenes-substitution, metal-halogen exchange, and skeletal cleavage. Use of these reaction pathways allows the synthesis of species such as I-X. A general mechanistic theory of these reactions is presented, together with an application of these mechanisms to macromolecular synthesis.Keywords
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