Many-Electron Effects in the Shape of theX-Ray Emission Lines
- 25 August 1986
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 57 (8) , 988-991
- https://doi.org/10.1103/physrevlett.57.988
Abstract
Fluorescent x-ray spectra were observed with a double-crystal spectrometer. line shapes appeared asymmetrically smeared by the presence of the shakeoff satellites within the natural width of main lines. Bonding effects of satellites—parasites—of chlorine were observed () for the first time. The relative intensities of parasites were measured in a number of chlorine compounds. Except for RbCl and CsCl, the relative intensities were found to be related to the covalency of the compounds.
Keywords
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