Backbone rearrangements of androst-5-ene and D-homoandrost-5-ene: a novel racemisation
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 16,p. 948-949
- https://doi.org/10.1039/c29710000948
Abstract
The title compounds rearrange under acidic conditions to give mixtures of 8(9)-enes; equilibration of configurations at C-5, C-10, C-13, and C-14 in the D-homo-compounds leads to complete loss of optical activity.Keywords
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