Oxofluorovanadates(V). II Dioxodifluorovanadates
- 1 September 1971
- journal article
- research article
- Published by Wiley in Zeitschrift für anorganische und allgemeine Chemie
- Vol. 384 (3) , 255-259
- https://doi.org/10.1002/zaac.19713840310
Abstract
The syntheses of ammonium, sodium, hexamminecobalt(III) and ethylene‐diamine dioxodifluorovanadate(V), MIVO2F2, are reported. Their x‐ray powder diffraction data are different from those of the corresponding tetrafluoroborates and perchlorates. Their infrared spectra have been recorded (700–4000 cm−1), and probable band assignments made. The ammonium dioxodifluorovanadate has been studied through thermogravimetry, and the composition of an intermediate product is discussed from its chemical analysis and infrared spectrum.Keywords
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