An isotopic and geochemical study of snowmelt runoff in a small arctic watershed

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Abstract
‘Old’ water contributions to snowmelt runoff in a stream can be defined as water which was stored in the catchment prior to the start of the runoff event in question. We used mass balance techniques for natural oxygen‐18 and several chemical parameters (electrical conductivity, Ca and Mg) to estimate the magnitude and timing of ‘old’ water contributions to snowmelt runoff in the Apex River watershed during the 1983 field season. The Apex River catchment is located in the southern part of Baffin Island, Northwest Territories, Canada. The watershed has an area of 60 km2, it is in the zone of continuous permafrost, and the geology is dominantly Precambrian gneiss with sporadic, thin, glacial overburden. The isotopic data indicate that for the snowmelt season of 1983 (third highest peak discharge of 11 years of record), approximately 50 per cent of the peak stream discharge consisted of ‘old’ water. Our data also suggest that about 60 per cent of the entire 1983 hydrograph was ‘old’ water. The chemical parameters give old water contributions which are at least 10 per cent less than the isotopically‐derived estimate, but they are consistent with the isotopic estimate during peak flow.