Cyclometallation, Palladium(II) Complexes with Schiff Base Ligands
- 1 January 1986
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 16 (4) , 499-511
- https://doi.org/10.1080/00945718608055924
Abstract
A number of new cyclometallated complexes of palladium with Schiff bases have been synthesized and characterized. These ligands with palladium(II) acetate gave the acetato-bridged dimers. These were converted to the corresponding halooeno-bridged dimers by reaction with sodium chloride or sodium bromide. Reaction of the latter complexes with P(C6H5)3 in a 1:2 molar ratio afforded the cyclometal lated phosphine monomers. All the compounds prepared in this study are characterized by means of IR and 1H NMD spectroscopy.Keywords
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