Rhodium-Catalyzed Conjugated Addition of Aryllead Reagents to α,β-Unsaturated Carbonyl Compounds in Air and Water

Abstract
In the presence of a rhodium catalyst, α,β-unsaturated esters and ketones (1a-f) react with phenyltrimethyllead 2 in aqueous media and under an air atmosphere to give the corresponding conjugated addition products (3a-e) in high yields.

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