The crystal structure of pyrite-related Rh3Se8

1 September 1968

journal article
research article
Published by Walter de Gruyter GmbH in Zeitschrift für Kristallographie

Vol. 127 (1-4) , 164-172
https://doi.org/10.1524/zkri.1968.127.1-4.164

Abstract

Rh 3 Se 8 crystallizes rhombohedrally with a = 5.9648 Å and α = 90°44′. With space group R [unk]– C 3 i 2 three Rh atoms are in 3 e , two Se in 2 c with x = 0.3816 and six Se in 6 f with x = 0.8877, y = 0.1166 and z = 0.6204. The structure of Rh 3 Se 8 is the first example of a pyrite-related structure with ordered metal defects.

Keywords

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