Organoimido ligands with remote functionality: a p-pyridylimido complex of vanadium(V) and its use as a metalloligand

Abstract
The exposed nitrogen atom of the p-pyridylimido ligand in the vanadium(V) species [(N3N)VN-C5H4N]1{N3N =[(Me3SiNCH2CH2)3N]3–} provides a reactive site capable of complexing a second metal fragment, enabling the construction of new types of heterobimetallic complexes linked by a compact conjugated bridge.

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