Reversible Combination of Carbon Monoxide with a Synthetic Oxygen Carrier Complex
- 6 May 1966
- journal article
- other
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 152 (3723) , 769-771
- https://doi.org/10.1126/science.152.3723.769
Abstract
Chlorocarbonyl-bis(triphenylphosphine)iridium(I), in solution, reacts reversibly with carbon monoxide under normal conditions, one molecule per metal atom. Formation of a 1 : 1 metal complex-CO adduct is verified by CO absorption measurements and the infrared spectrum of the adduct measured in situ. The spectrum suggests that the metal-C-O bonding is of the type found in conventional metal carbonyl.Keywords
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