Allylic sulfones as allyl anion equivalents: homoallylic alcohols from metal catalysed reactions of sulfones with aldehydes and ketones
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1905-1906
- https://doi.org/10.1039/c39940001905
Abstract
Reduction of allylic sulfones with diethylzinc, catalysed by palladium(0), gives nucleophilic organometallic species, which react in situ with carbonyl compounds to give homoallylic alcohols in high yield.Keywords
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