Perfect complementarity in the fitting of two homochiral heterodonor ligands around a nickel(II) centre: an ‘intramolecular embrace’
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 9,p. 1421-1422
- https://doi.org/10.1039/a801170b
Abstract
The homochiral form of the complex [(‘P,N’)2Ni]2+ (‘P,N’ is a phosphino–heteroatom bidentate ligand) has been found to be more stable than its heterochiral analogue due to a ‘fitting’ of the two ‘P,N’ ligands about the Ni that is reminiscent of an ‘intramolecular embrace’.Keywords
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