Iron(II)‘hanging imidazole’ porphyrin: synthesis and proximal ligand effect on CO and O2binding
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 962-964
- https://doi.org/10.1039/c39830000962
Abstract
The preparation of the title compound, a model for the active site of oxygen carrier hemoproteins, is described and the kinetic parameters of the CO and O2 adducts show the importance of the co-ordinated imidazole in stabilization.Keywords
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