Arene molybdenum chemistry: tertiary-phosphine and -phosphite derivatives and related phosphine-hydrides
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2929-2931
- https://doi.org/10.1039/j19710002929
Abstract
Treatment of bis(benzene)molybdenum with tertiary-phosphines or -phosphites gives the derivatives C6H6MoL3[L = PPhMe2, PPh2Me, P(OMe)3, PPh2(OMe), or P(OPh)3]. When L = PPh2Me or PPhMe2 the compounds are basic and readily protonate forming the hydrides [C6H6MoL3H]+.Keywords
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