Polycyclic fluoro-aromatic compounds. Part 9. Preparation and some reactions of decafluorofluoranthene
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 1726-1730
- https://doi.org/10.1039/p19800001726
Abstract
Fluorinations of fluoranthene with cobalt trifluoride and potassium tetrafluorocobaltate give perfluoroperhydrofluoranthene and perfluorotetradecahydrofluoranthene, respectively. Defluorination of either of these over iron(II) oxide gives decafluorofluoranthene, which is attacked by nucleophiles (OMe–, H–, NH2NH2) at position 1, and then at 6, 3, and 4. Oxidation of decafluorofluoranthene with nitric acid gives octafluorofluoranthene-2,3-quinone and then heptafluoro-9-oxofluorene-1-carboxylic acid.Keywords
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