Solid-Phase Synthesis of a Phytoalexin Elicitor-Active Tetraglucosyl Glucitol

Abstract
A solid-phase synthesis of pentasaccharide 1 that has phytoalexin elicitor activity for rice is described. Efficient block-type synthesis by β-selective glycosylation with thioglycosides A 3 and B 2 at the 3-position of the polymer-supported glycosyl acceptor has been demonstrated.

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