The formation of nanoparticulate cobalt carbide, Co2C, encapsulated in an amorphous siliceous matrix
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 2065-2066
- https://doi.org/10.1039/c39950002065
Abstract
Reaction of octahydridooctasesquisiloxane with Co2(CO)8 in hexane affords the complex [Si8O12H6]{Co(CO)4}2 which on pyrolysis at 300 °C in vacuo gives nanoparticulate Co2C encapsulated in an amorphous siliceous matrix; the magnetic coercivity of this material is 3.5 kOe.Keywords
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