Conversion of Amides toS-Alkyl andS-Aryl Thioesters via Nitrosoamides and Nitroamides
- 1 January 1989
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1989 (04) , 305-306
- https://doi.org/10.1055/s-1989-27234
Abstract
Thiolates react at room temperature with nitrosoamides and, even more rapidly, with nitroamides to afford good yields of S-alkyl and S-aryl thioesters; by-products arising from N-to-S transnitrosations and transnitrations are practically not observed.Keywords
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