Rearrangements Involving alkoxycarbonyl group migration between nitrogen and oxygen.III. Reactions of modified isoquinoline Reissert compounds with aldehydes
- 1 January 1977
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 55 (1) , 164-170
- https://doi.org/10.1139/v77-028
Abstract
The condensation reaction of modified Reissert compounds with aldehydes was investigated. In the reaction of the N-ethoxycarbonyl Reissert analog 1b, ethoxycarbonyl group migration takes place and carbonates of 1-isoquinolylphenylcarbinols (2b, c) are formed. No alkoxycarbonyl group migration was observed in the case of the dihydro-Reissert derivative 6, but the cyclic urethane 7 and the amide 8 were obtained.Keywords
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