Masking the carboxy group as a 2,6,7-trioxabicyclo[2.2.2]octane: application to the synthesis of alkylcobaloximes containing ester and carboxy groups
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 207-208
- https://doi.org/10.1039/c39800000207
Abstract
The hydrolytic stability of 2,6,7-trioxabicyclo-[2.2.2]octanes towards aqueous acid is intermediate between that of 1,1,1-triethoxyethane and 1-methyl-2,8,9-trioxa-adamantane; a synthetic application of this trioxabicyclo-octane group as a masked carboxy function is described.Keywords
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