The synthesis, structure and magnetic properties of a cyclic dodecanuclear nickel complex
- 1 January 1994
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 2363-2364
- https://doi.org/10.1039/c39940002363
Abstract
The synthesis and characterisation of the dodecanuclear nickel complex, [Ni12(O2CMe)12(chp)12(H2O)6(THF)6](where chp = the anion of 6-chloro-2-pyridone) is described; structure determination shows formation of a metallocycle, while magnetic studies indicate ferromagnetic coupling between the nickel(II) ions within the complex leading to a high spin multiplicity in the ground state.Keywords
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