Some phosphine-substituted carbonyl-π-cyclopentadienyl complexes of molybdenum and tungsten
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2291-2294
- https://doi.org/10.1039/j19680002291
Abstract
The preparation of some new complexes of the type [(π-C5H5)M(CO)2(L)]2Hg and (π-C5H5)M(CO)2(L)HgX [M = Mo, W; L = P(OMe)3, P(OPh)3, PPh3; X = Cl, Br, I] is reported. These are reduced by sodium amalgam, and subsequent treatment with acetic acid or methyl iodide yields new hydride and alkyl complexes. Many of the complexes exist in solution as mixtures of two isomers and the equilibrium between these has been investigated.Keywords
This publication has 0 references indexed in Scilit: