Conjugate addition of internal nucleophile to chiral vinyl sulfoxides with stereogenic center at the allylic carbon. “intramolecular” double asymmetric induction
- 1 January 1988
- journal article
- Published by Elsevier in Tetrahedron Letters
- Vol. 29 (25) , 3121-3124
- https://doi.org/10.1016/0040-4039(88)85102-5
Abstract
No abstract availableKeywords
This publication has 11 references indexed in Scilit:
- Stereodivergent total synthesis of N-acetylacosamone and N-benzoylristosamineThe Journal of Organic Chemistry, 1987
- Modeling chemical reactivity. 3. Stereochemistry of Michael additions of vinyl sulfoxidesJournal of the American Chemical Society, 1986
- Asymmetric intramolecular conjugate addition of amines to chiral vinyl sulphoxides. Total synthesis of (R)-(+)-carnegineJournal of the Chemical Society, Chemical Communications, 1986
- New acyclic apporach to 3-amino-2,3,6-trideoxy-L-hexoses: a stereocontrolled synthesis of N-benzoylL-daunosamineJournal of the Chemical Society, Chemical Communications, 1986
- Reversal of diastereofacial selectivity in the intramolecular michael addition of -α-carbamoyloxy-α,β-unsaturated esters. Synthesis of N-benzoyl-Tetrahedron Letters, 1985
- Carbamate-mediated functionalization of unsaturated alcohols. 3. Intramolecular Michael addition of O-carbamates to .alpha.,.beta.-unsaturated esters. A new diastereoselective amination in an acyclic systemJournal of the American Chemical Society, 1985
- Diastereoselective synthesis of N-acetyl-,-acosamine and N-benzoyl-,-ristosamineTetrahedron Letters, 1985
- HETEROCONJUGATE ADDITION OF LITHIUM ALKYLS TO SUBSTITUTED HETERO-OLEFINS CONJUGATED WITH SULFUR AND SILICON ATOMSChemistry Letters, 1980
- Intramolecular Cyclizations of Thioureas Derived from Sulphoraphene: a Case of Asymmetrically Induced Additions to Vinylic Sulphoxides.Acta Chemica Scandinavica, 1974
- Allylic strain in six-membered ringsChemical Reviews, 1968