Prostaglandin analogs possessing antinidatory effects. 1. Modification of the .omega. chain

Abstract
Novel prostaglandin [PG] analog modified in the .omega. chain were prepared by the reaction of the vinyl aldehydes with a variety of organometallic reagents as a key step of the synthesis. Compared with the natural PGF2.alpha. in antinidatory effect, the analogs 17-oxo-17-phenyl-18,19,20-trinorprostaglandin F2.alpha. methyl ester, 16,16,17,17-tetrahydro-17-phenyl-18,19,20-trinorprostaglandin F2.alpha. methyl ester and 15-(2-benzo[b]thienyl)-16,17,18,19,20-pentanorprostaglandin F2.alpha. methyl ester were 40 times more potent and 15-(2-benzofuranyl)-16,17,18,19,20-pentanorprostaglandin F2.alpha. methyl ester was 50-100 times more potent in the rat.

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