Conductive mixed-halide adducts of tetrathiafulvalene obtained by electrocrystallisation
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 378-379
- https://doi.org/10.1039/c39810000378
Abstract
The electrocrystallised mixed-halide TTFBr0·23– I0·46 and TTFBr0·47I0·24(TTF = tetrathiafulvalene) have Br:I ratios which are dependent on the solution composition, with the total halide stoicheiometries approximating the single-halide values in TTFBr0·76 and TTFI0·71, the maximum conductivities at 25 °C being intermediate between the single-halide values of 1600 and 42·5 Ω–1, respectively (cf. 2800 and 34 Ω–1cm–1, respectively); single-axis structure data are comparable throughout.Keywords
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