Syntheses of anomeric glucopyranosylidene diazides
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 431-432
- https://doi.org/10.1039/c39900000431
Abstract
Protected glucopyranosylidene diazides have been obtained in good yields by two routes which involve nucleophilic substitutions at the anomeric polsition of either 2,3,4,6-tetra-O-acetyl-1-bromo-β-D-glucopyranosyl chloride or 2,3,4,6-tetra-O-benzyl-D-glucono-1,5-lactone, in the presence of silver azide or trimethylsilyl azide, respectively.Keywords
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