Anion-Exchange in Basic Copper Acetate
- 1 October 1989
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 18 (10) , 1869-1872
- https://doi.org/10.1246/cl.1989.1869
Abstract
Basic copper acetate, Cu2(OH)3(OCOCH3)·H2O has the layer structure of the botallackite type. The acetate ions are located between the positively charged copper hydroxide layers and exchangeable with various anions such as NO3−, ClO4−, Cl−, Br−, I− and carboxylate ions. The exchange reactions are topotactic and some are reversible.Keywords
This publication has 8 references indexed in Scilit:
- Anionic surfactants between double metal hydroxide layersJournal of Colloid and Interface Science, 1988
- Layered double hydroxides (LDHs)Solid State Ionics, 1988
- Role of ion exchange in solid-state chemistryChemical Reviews, 1988
- Synthesis of anionic clay minerals (mixed metal hydroxides, hydrotalcite)Solid State Ionics, 1986
- Anion intercalation and exchange in Al(OH)3-derived compoundsJournal of Solid State Chemistry, 1985
- Über die Hydroxidhalogenide Me2(OH)3Cl, ‐Br, ‐J zweiwertiger Metalle (Me = Mg, Ni, Co, Cu, Fe, Mn)Helvetica Chimica Acta, 1964
- Die Kristallstrukturbestimmung des monoklinen, basischen Kupfernitrates Cu4(NO3)2 (OH)6 IIHelvetica Chimica Acta, 1952
- The Equilibria of Cupric Hydroxysalts in Mixed Aqueous Solutions of Cupric and Alkali Salts at 25°Journal of the American Chemical Society, 1949