Reversible hydrogen gas uptake in nanoporous Prussian Blue analogues
- 27 May 2005
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 26,p. 3322-3324
- https://doi.org/10.1039/b502850g
Abstract
The family of dehydrated nanoporous Prussian Blue analogues, MII 3[CoIII(CN)6]2 (MII = Mn, Fe, Co, Ni, Cu, Zn, Cd), which contain coordinatively unsaturated divalent metal cations, undergoes reversible sorption of hydrogen gas up to 1.2 wt% (at 77 K, 101.3 kPa), the capacity of which depends on the metal ion.Keywords
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