On the Free Energy of Solutions
- 1 February 1956
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 24 (2) , 357-359
- https://doi.org/10.1063/1.1742477
Abstract
The proposal has been made that the free energy of a mixture is (aside from the free energy of mixing) equal to the sum of the free energies of the pure components computed at a reduced temperature and reduced volume characteristic of the environment of the molecules in the solution. This proposal is tested for a simple model, the generalized cell model for solutions, and found to be a good approximation.Keywords
This publication has 5 references indexed in Scilit:
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- The cell theory of liquid mixturesTransactions of the Faraday Society, 1953
- Application of the Cell Method to the Statistical Thermodynamics of SolutionsThe Journal of Chemical Physics, 1952
- Lennard-Jones and Devonshire Equation of State of Compressed Gases and LiquidsThe Journal of Chemical Physics, 1950
- Critical phenomena in gases - IProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1937