Simple syntheses of glycofuranosylamines derived from D-xylose, D-mannose, and L-rhamnose, intermediates in the preparation of some N-glycofuranosyl uracils
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 4,p. 190-191
- https://doi.org/10.1039/c29710000190
Abstract
3,5-O-Isopropylidene-D-xylofuranosylamine, 2,3-O-isopropylidene-L-rhamnofuranosylamine, and 2,3:5,6-di-O-isopropylidene-D-mannofuranosylamine have been prepared in high yield as toluene-p-sulphonates by reaction of the corresponding pyranosylamines with acetone, 2,2-dimethoxypropane, and toluene-p-sulphonic acid; the glycofuranosylamines have been used to prepare pyrimidine nucleosides.Keywords
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