Über die Reaktion von Thallium(I)-Sulfid mit den Disulfiden von Vanadium, Niob, Tantal und Molybdän / On the Reaction of Thallium(I) Sulfide with the Disulfides of Vanadium, Niobium, Tantalium and Molybdenum
Open Access
- 1 February 1973
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 28 (1-2) , 25-28
- https://doi.org/10.1515/znb-1973-1-208
Abstract
Tl2S reacts with VS22 to Τl3VS4 and VS. With NbS2 and TaS2 the analogous thiometallates(V) are obtained. The metallic thallium hereby produced gives with NbS2 and probably with TaS2 an intercalation-phase TlXNb(Ta)S2. There is no reaction between Tl2S and MoS2 up to 500°C. Thallium(I)-thiometallates(IV), Tl2MeS3, described in literature do not exist.Keywords
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