A Porous Coordination Copolymer with over 5000 m2/g BET Surface Area
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- 6 March 2009
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 131 (12) , 4184-4185
- https://doi.org/10.1021/ja809985t
Abstract
New levels of surface area are achieved in a coordination polymer (UMCM-2, University of Michigan Crystalline Material) derived from zinc-mediated coordination copolymerization of a dicarboxylic and tricarboxylic acid. In addition to a large micropore contribution to the surface area, mesopores are also present. In contrast to the recently reported coordination copolymer UMCM-1, which has a mesoporous channel, UMCM-2 is built from three types of cages. In spite of exceptional porosity, both of these coordination polymers are thermally robust. Hydrogen uptake performance of UMCM-2 approaches 7 wt% at 77 K.Keywords
This publication has 13 references indexed in Scilit:
- Phase Selection and Discovery among Five Assembly Modes in a Coordination PolymerizationInorganic Chemistry, 2008
- A Crystalline Mesoporous Coordination Copolymer with High MicroporosityAngewandte Chemie International Edition in English, 2008
- Crystal Structure and Guest Uptake of a Mesoporous Metal–Organic Framework Containing Cages of 3.9 and 4.7 nm in DiameterAngewandte Chemie International Edition in English, 2007
- Calculating Geometric Surface Areas as a Characterization Tool for Metal−Organic FrameworksThe Journal of Physical Chemistry C, 2007
- Applicability of the BET Method for Determining Surface Areas of Microporous Metal−Organic FrameworksJournal of the American Chemical Society, 2007
- Hydrogen storage in metal–organic frameworksJournal of Materials Chemistry, 2007
- Exceptional H2 Saturation Uptake in Microporous Metal−Organic FrameworksJournal of the American Chemical Society, 2006
- A route to high surface area, porosity and inclusion of large molecules in crystalsNature, 2004
- Characterization of Porous Solids and Powders: Surface Area, Pore Size and DensityPublished by Springer Nature ,2004
- From Molecules to Crystal Engineering: Supramolecular Isomerism and Polymorphism in Network SolidsChemical Reviews, 2001