On a so-called “kinetic anomeric effect” in chemical glycosylation
- 1 January 2012
- journal article
- Published by Royal Society of Chemistry (RSC) in Organic & Biomolecular Chemistry
- Vol. 10 (13) , 2503-2508
- https://doi.org/10.1039/c2ob06696c
Abstract
Commentary on diastereoselectivity in chemical glycosylation reactions, and dismissal of the influence of stereoelectronic effects analogous to the anomeric effect in kinetically controlled reactions.Keywords
This publication has 48 references indexed in Scilit:
- Remote Participation of Protecting Groups at Remote Positions of Donors in GlycosylationsTrends in Glycoscience and Glycotechnology, 2011
- Influence of the O3 Protecting Group on Stereoselectivity in the Preparation ofC-Mannopyranosides with 4,6-O-Benzylidene Protected DonorsThe Journal of Organic Chemistry, 2010
- Computational evidence that hyperconjugative interactions are not responsible for the anomeric effectNature Chemistry, 2010
- Theoretical Investigation of Solvent Effects on Glycosylation Reactions: Stereoselectivity Controlled by Preferential Conformations of the Intermediate Oxacarbenium-Counterion ComplexJournal of Chemical Theory and Computation, 2010
- Toward solution-phase automated iterative synthesis: fluorous-tag assisted solution-phase synthesis of linear and branched mannose oligomersOrganic & Biomolecular Chemistry, 2008
- Automated Solid-Phase Synthesis of OligosaccharidesScience, 2001
- Programmable One-Pot Oligosaccharide SynthesisJournal of the American Chemical Society, 1999
- Chemically Synthesized Oligosaccharides, 1994. A Searchable Table of Glycosidic Linkages.Journal of Carbohydrate Chemistry, 1995
- Long Range Intramolecular GlycosidationChemistry Letters, 1994
- The conformational properties of glycosidic linkagesTetrahedron, 1974