Diplatinum(III) tetrakis(β-diketonato) complexes exemplifying the unsupported Pt–Pt bond
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 19,p. 2271-2272
- https://doi.org/10.1039/cc9960002271
Abstract
Coupling of tervalent ClPt(acac)2 moieties to form diamagnetic, directly Pt–Pt bonded [Pt2Cl2(acac)4] occurs in the course of oxidative addition of Cl2 to [Pt(acac)2][acac = R(CO)CH(CO)R′ and R/R′= Me/Me, Me/CF3 or Ph/Ph].Keywords
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