A quantitative study of enrichment of K+in radical–ion pairs generated by sodium reduction
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 239-240
- https://doi.org/10.1039/c39940000239
Abstract
ESR spectroscopy and atomic absorption measurements establish that K+ enrichment up to four orders of magnitude may occur when reduction reactions are performed using even highly pure Na sources.Keywords
This publication has 6 references indexed in Scilit:
- Radical Anions of Cyclic Azoalkanes: An ESR, ENDOR, and TRIPLE‐Resonance StudyHelvetica Chimica Acta, 1991
- Comment on “association between lithium biphenylide and biphenyl”Chemical Physics Letters, 1986
- ESR and ENDOR studies of a radical anion with formally nonconjugated keto groups: cis-10,11-dimethyldiphensuccindan-9,12-dioneJournal of the American Chemical Society, 1979
- Intramolecular cation exchange in ion pairs. Part I. Alkali metal complexes of heterocyclic dicarbaldehydesJournal of the Chemical Society, Perkin Transactions 2, 1973
- Comment on Nonreproducible ESR Absorption Spectra of Solutions of Aromatic Hydrocarbons Reduced with Alkali MetalsThe Journal of Chemical Physics, 1969
- Nonreproducible ESR Absorption Spectra of Solutions of Aromatic Hydrocarbons Reduced with Alkali MetalsThe Journal of Chemical Physics, 1969