Stereoconservative Negishi arylation and alkynylation as an efficient approach to enantiopure 2,2′-diarylated 1,1′-binaphthyls
- 1 October 2004
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 22,p. 2606-2607
- https://doi.org/10.1039/b410185e
Abstract
Negishi arylation and alkynylation of easily synthesized chiral 2,2′-diodo-1,1′-binaphthyl rapidly proceeds in refluxing THF utilizing controlled microwave irradiation, affording enantiopure 2,2′-diarylated 1,1′-binaphthyls in good to excellent yields.Keywords
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