Synthesis, Structure and Catalytic Activity of An Oxorhenium(V) Complex Containing Chelating Phosphite Ligand
- 1 January 1992
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 26 (1) , 79-82
- https://doi.org/10.1080/00958979209407915
Abstract
The new violet oxorhenium(V) complex ReOCl3(pinacop) {pinacop = (OCMe2CMe2O)POCMe2CMe2OP (OCMe2CMe2O)} was obtained by reaction of ReOCl3(OPPh3)(SMe2) with a stoichiometric amount of pinacop. Facial geometry was determined by spectroscopic means and preliminary results from an X-ray crystallographic study. The catalytic properties of the title compound in oxygen atom transfer reactions are discussed.Keywords
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