Synthesis, molecular structure, and reactions of bis(tetraphenylphosphonium) hexakis(.mu.-thiophenolato)-tetrachlorotetraferrate(II), (Ph4P)2[Fe4(SPh)6Cl4]. Its reactions with dibenzyl trisulfide and the synthesis of the [Fe4S4Cl4]2- and [Fe4S4(Cl)2(SC6H5)2]2- "Cubane"-type clusters
- 1 April 1982
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 104 (7) , 1874-1882
- https://doi.org/10.1021/ja00371a016
Abstract
No abstract availableThis publication has 4 references indexed in Scilit:
- Tetrahedral complexes containing the Fe(II)S4 core. The syntheses, ground-state electronic structures and crystal and molecular structures of the bis(tetraphenylphosphonium) tetrakis (thiophenolato)ferrate (II) and bis (tetrapheny lphosphonium) bis(dithiosquarato)ferrate (II) complexes. An analog for the active site in reducd rubredoxins (Rdred)Journal of the American Chemical Society, 1981
- Formation, crystal structure, and reactions of catena-(.mu.-SPh)[(.mu.-SPh)6Zn4(CH3OH)(SPh)], a model for zinc thiolate metalloenzymesJournal of the American Chemical Society, 1980
- Iron-sulfur clusters in Azotobacter ferredoxin at 2.5 A resolution.Journal of Biological Chemistry, 1980
- Reaction chemistry of the iron-sulfur protein site analogs [Fe4S4(SR)4]2-. Sequential thiolate ligand substitution reactions with electrophilesJournal of the American Chemical Society, 1978