Phenylation of Platinum(II) Thioether Complexes by Tetraphenylborate(III) in Solid State and Nitromethane Solution
- 1 February 1993
- journal article
- research article
- Published by Taylor & Francis in Phosphorus, Sulfur, and Silicon and the Related Elements
- Vol. 75 (1-4) , 253-255
- https://doi.org/10.1080/10426509308037400
Abstract
Platinum(II) complexes of the type [Pt(thioether)3Cl]+ (thioether = dimethyl sulfide, thioxane) are capable of abstracting a phenyl group from the BPh− 4 counterion with formation of trans-[Pt(thioether)2ClPh] compounds. Thermal reactions proceed both in the solid phase and in nitromethane solution at elevated temperature and have preparative importance. Phenylation of the Pt(II) centre also occurs in reaction between [Pt(Me2S)2Cl2] and AgBPh4 in CH2Cl2 suspension. Brief X-ray crystallographic structural data for trans-[Pt(Me2S)2ClPh] and [Pt(thioether)3Cl]X (thioether = Me2S, tx, X = SO3CF3; thioether = Me2S, X = PF6) are reported.Keywords
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