Nuclear magnetic resonance study of soft-mode dynamics in the nematic phase of- azoxyanisole
- 1 June 1978
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 17 (6) , 2062-2066
- https://doi.org/10.1103/physreva.17.2062
Abstract
The critical slowing down of the optical soft mode, or the order-parameter fluctuation, in the nematic phase of methyl-deuterated -azoxyanisole is detected for the first time by combining the proton spin-lattice relaxation times in the laboratory and in the rotating frames. Freed's recent theory of spin relaxation by quasicritical order-parameter fluctuations is used to satisfactorily interpret our NMR measurements. The present study confirms the mean-field prediction of symmetry in critical order-parameter fluctuations at isotropic-nematic transitions.
Keywords
This publication has 14 references indexed in Scilit:
- Stochastic-molecular theory of spin–relaxation for liquid crystalsThe Journal of Chemical Physics, 1977
- A proton and deuteron spin–lattice relaxation study of the partially deuterated nematogens PAA and MBBAThe Journal of Chemical Physics, 1977
- Theory for spin-lattice relaxation in nematic liquid crystalsPhysical Review A, 1976
- 14N NMR Study of Order Fluctuations in the Isotropic Phase of Liquid CrystalsMolecular Crystals and Liquid Crystals, 1976
- Nuclear Spin-Lattice Relaxation in Liquid Crystals by Fluctuations in the Nematic DirectorPhysical Review Letters, 1974
- Soft-mode dynamics in nematic liquid crystalsPhysical Review A, 1974
- Short Range Order Effects in the Isotropic Phase of Nematics and CholestericsMolecular Crystals and Liquid Crystals, 1971
- Effects of Order and Fluctuations on theNMR in a Liquid CrystalPhysical Review Letters, 1970
- Phenomenology of short-range-order effects in the isotropic phase of nematic materialsPhysics Letters A, 1969
- Nuclear relaxation in a nematic liquid crystalSolid State Communications, 1969