Synthesis and electrochemistry of crown ether dithiolene complexes
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 12,p. 3789-3792
- https://doi.org/10.1039/dt9900003789
Abstract
The syntheses of copper and bis(η-cyclopentadienyl)molybdenum complexes of a dithiolene ligand incorporating a trioxadithia-15-crown-5-unit [1,4,7-trioxa-10,13-dithiacyclopentadec-11-ene-11,12-dithiolate(2–)] are described. The electrochemistry of these complexes was investigated by cyclic voltammetry in acetonitrile. Upon addition of an excess of alkali-metal cations large shifts of the redox potentials of the compounds were observed.Keywords
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